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Electrolyte pH does not change significantly in alkaline solutions compared to acid solutions. In alkaline baths, the variation of metal percent in deposit with current density is less significant, but that of current efficiency with current density is more. Compared to alkaline baths, acid baths offer higher metal percent of the alloying element and higher current efficiency. Zinc–cobalt (Zn–Co) and zinc–nickel (Zn–Ni) alloy electrodeposits each prepared from acid and alkaline formulations were compared for their properties.
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